Mechanism of the CuII-catalyzed benzylic oxygenation of (aryl)(heteroaryl)methanes with oxygen

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oxidation of benzylic alcohols with molecular oxygen catalyzed by cu3/2[pmo12o40]/sio2

the aerobic oxidation of alcohols was efficiently completed in high conversion and selectivity using cu3/2[pmo12o40]/sio2 as catalyst under mild reaction condition. this reaction provides a new environmentally friendly rout to the conversion of alcoholic function to carbonyl groups.

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ژورنال

عنوان ژورنال: Chemical Science

سال: 2016

ISSN: 2041-6520,2041-6539

DOI: 10.1039/c5sc03530a